The team of six is completed by Cesc Fabregas, Lionel Messi and Frank Lampard, who will all star in a multimillion-pound TV ad set to be launched next month.
The , which features a section called 'Youniverse' where users can set up their own profile, features a behind-the-scenes video of the making of the ad, with commentary from all six footballers. It was created by British website developer .
The campaign is being launched to enable Pepsi to engage young consumers through the power of social networking.
The soft drinks giant is planning to add other celebrities, including musicians, to the social networking site in the coming months.
Separately, Pepsi has become embroiled in a row with retailers in the US over a recent ad campaign it launched in conjunction with online retailer .
The campaign is part of a drive to increase traffic to its recently launched music download site. It was backed by an ad featuring Justin Timberlake, which made its debut during the high profile Super Bowl ad break in February.
The campaign has upset traditional high street retailers who account for the largest part of sales.
The retailers are understood to be particularly upset about the prominence of Amazon logos on the back of cardboard multi-pack cartons that are stacked on the supermarket's shelves.
In a response to the outcry, Amazon's name has been removed from the front of Pepsi bottles carrying the logo.