There was an overall 9.1% rise in the value of exports between 2006 and 2007.
Chris Brockman, research and consultancy manager at Food from Britain, the government agency promoting food export, said: "Breaking the £10bn barrier in 2006 was incredibly significant, it was the first time since the BSE outbreaks that the export market has reached these levels of business."
Exports to Poland increased by 54.7% to £47m, as Polish immigrants to the UK discovered British brands and popularised them in their native land.
Tetley and Twinings tea, oriental food range Blue Dragon, and Spitfire and Bombardier beer from Britain's oldest brewer, Shepherd Neame, were among the most popular.
Tesco operates over 100 superstores in Poland and stocks a range of British favourites and delicacies.
Ireland continues to be the number one export market with a value of £2.24bn. France is the UK's second largest export destination with a value of £1.38bn. Britain's biggest export is Scotch whisky.