The includes denim, lingerie, dresses and outwear products.
The move follows speculation that Amazon would make aggressive moves into the fashion market with a bid for online retailer Asos.
Rival online pure-play retailer eBay has already made inroads into fashion and, in the summer, , which supports emerging design talent.
Jessica Brown, head of fashion at Amazon UK, said: "The new store brings together the latest, must-have women's fashion brands and marks the introduction of some of our favourite US denim brands at Amazon.co.uk.
"In addition to big-name labels like 7 For All Mankind, the store also offers cult denim labels such as Siwy, giving customers a great breadth of designer styles to choose from."
The launch of the store comes at a time when Amazon is coming under increasing pressure to restructure its complex company structure that allowed Amazon.co.uk to .
Starbucks has already bowed to pressure and has revealed saying it understands "we need to do more to maintain and further build public trust".
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