The List allows fans to view exclusive video recordings of artist performances held in intimate venues. There are already more than three million users on the site.
For the programme's international debut, MySpace carried a Hollywood gig by My Chemical Romance, previewing music from the group's new album, The Black Parade.
Jamie Kantrowitz, senior vice-president of marketing and content, Europe, for MySpace, said: "MySpace connects artistes with fans and this international programme will allow millions of users around the world to see unique performances by some of the greatest acts on the planet.
"The internet has been a huge part of taking artistes global in a very short span of time and The List takes MySpace Music a step further."
The new service follows MySpace's Secret Shows franchise launched in August, which offered users the chance to see exclusive secret gigs from bands such as Primal Scream and The Magic Numbers.