The review is beginning immediately and effects all its business, including snacks, food and pet care.
A spokeswoman said the review was aimed at "increasing the effectiveness" of the company's media spend. Masterfoods brands include Mars, Snickers, M&Ms, Twix, Pedigree and Whiskas pet food, and Uncle Ben's rice.
The confectionery and food giant's media business is currently split between OMD, owned by Omnicom; Grey Global-owned MediaCom; Publicis group's MediaVest and WPP Group's Mediaedge:cia.
Publicis-owned ZenithOptimedia, which handles sports buying in the US, is reported not to be pitching.
Last year, the £120m European planning work was handed to MediaCom, after a pitch against fellow incumbents Starcom MediaVest Group and PHD, as well as ZenithOptimedia Group and Media Planning Group, while ZenithOptimedia handles media buying in Europe.
If you have an opinion on this or any other issue raised on Brand Republic, join the debate in the .